By Dougal Drysdale(auth.)
Chapter 1 fireplace technological know-how and Combustion (pages 1–34):
Chapter 2 warmth move (pages 35–82):
Chapter three Limits of Flammability and Premixed Flames (pages 83–119):
Chapter four Diffusion Flames and fireplace Plumes (pages 121–179):
Chapter five regular Burning of beverages and Solids (pages 181–223):
Chapter 6 Ignition: The Initiation of Flaming Combustion (pages 225–275):
Chapter 7 unfold of Flame (pages 277–315):
Chapter eight Spontaneous Ignition inside Solids and Smouldering Combustion (pages 317–348):
Chapter nine The Pre?Flashover Compartment hearth (pages 349–386):
Chapter 10 The Post?Flashover Compartment fireplace (pages 387–439):
Chapter eleven Smoke: Its Formation, Composition and circulation (pages 441–474):
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Additional info for An Introduction to Fire Dynamics, Third Edition
18, the final (adiabatic) flame temperature can be shown to be 1228◦ C (1501 K), well below that at which the effect of dissociation is significant. 20). There is evidence to suggest that the same value also applies to the upper flammability (fuel-rich) limit (Mullins and Penner, 1959; Stull, 1971), but it cannot be derived by the same method as the lower limit because the products will contain a complex mixture of pyrolysis and partially oxidized products from the parent fuel. It should be noted that the temperature increases reported above will be accompanied by expansion of the gases.
Assume ideal gas behaviour. 2 Assuming ideal gas behaviour, what will the final volume be if 1 m3 of air is heated from 20◦ C to 700◦ C at constant pressure? 3 Calculate the vapour pressure of the following pure liquids at 0◦ C: (a) n-octane; (b) methanol; (c) acetone. 4 Calculate the vapour pressures of n-hexane and n-decane above a mixture at 25◦ C containing 2% n-C6 H14 + 98% n-C10 H22 , by volume. Assume that the densities of pure n-hexane and n-decane are 660 and 730 kg/m3 , respectively and that the liquids behave ideally.
Ethene and ethyne) are less stable than the parent elements and are known as endothermic compounds. Under appropriate conditions they can be made to decompose with the release of energy. Ethyne (acetylene), which has a large positive heat of formation, can decompose with explosive violence. 3 kPa) and an ambient temperature of 298 K (25◦ C) and to complete combustion. , water as a product is in the vapour state. 44 kJ/g (44 kJ/mol) at 25◦ C). 4) is less than unity. The actual heat released could be estimated by using Hess’ law of constant heat summation if the composition of the combustion products was known.